4-Allyl-2-meth­oxy­phenyl 3,4-dichloro­benzene­sulfonate

نویسندگان

  • Ya-Tuan Ma
  • Zhao-Feng Gao
  • Qi-Chao Liu
  • Gang Jin
  • Jin-Ming Gao
چکیده

The title compound, C(16)H(14)Cl(2)O(4)S, was obtained by the reaction of eugenol (4-allyl-2-meth-oxy-phenol) and 3,4-dichloro-benzene-sulfonyl chloride. The dihedral angle between the benzene rings in the mol-ecule is 40.53 (4)°. No significantly short inter-molecular contacts are observed in the crystal structure.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

4-Allyl-2-meth­oxy­phenyl 2-acet­oxy­benzoate

In the title compound, C(19)H(18)O(5), the ester group is twisted with respect to the acetyl-salicylic acid and eugenol rings at dihedral angles of 22.48 (2) and 81.07 (1)°, respectively. The dihedral angle between the two benzene rings is 60.72 (1)°. The crystal packing exhibits no significantly short inter-molecular contacts.

متن کامل

Isomerization of Allyl Ethers of Diols and Triols Catalyzed by Ruthenium Complexes

The allyl and propenyl ethers of diols and polyols have recently attracted increasing attention as monomers and comonomers [1–2]. Most convenient method of the preparation of propenyl ethers consists in isomerization of the corresponding, readily available allyl ethers. Moreover, this isomerization is a key step of deprotection of hydroxyl group, protected as allyl ether [3,4]. Particularly con...

متن کامل

6-Allyl-8-meth­oxy-3-phenyl-3,4-dihydro-2H-benzo[e][1,3]oxazine

In the title compound, C(18)H(19)NO(2), the allyl group is disordered over two sets of sites [occupancy ratio 0.662 (4):0.338 (4)]. The dihedral angle between the phenyl and benzene rings is 87.44 (10)°. The oxazinane ring adopts a sofa conformation.

متن کامل

Structure-activity studies of the carcinogenicities in the mouse and rat of some naturally occurring and synthetic alkenylbenzene derivatives related to safrole and estragole.

Twenty-three naturally occurring and synthetic alkenylbenzene derivatives structurally related to the hepatocarcinogen safrole (1-allyl-3,4-methylenedioxybenzene) were assayed for their hepatocarcinogenicity in mice. Some of these compounds (safrole, estragole, eugenol, anethole, methyleugenol, myristicin, elemicin, and dill and parsley apiols) may be ingested in very small amounts by human as ...

متن کامل

UV-induced photochemistry of matrix-isolated 1-phenyl-4-allyl-tetrazolone.

The photochemistry and molecular structure of 1-phenyl-4-allyl-tetrazolone (PAT) was studied by FT-IR matrix isolation spectroscopy and DFT(B3LYP)/6-311++G(d,p) calculations. The spectrum of matrix-isolated PAT monomers agrees well with the sum spectrum of three conformers predicted theoretically. UV irradiation (lambda > 235 nm) of matrix-isolated PAT induces three types of photofragmentation:...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011